Tetik Mehmet Ali, Sevindik Onur, Kelebek Hasim, Selli Serkan
Food Engineering Department, Faculty of Agriculture, University of Cukurova, 01330, Adana, Turkey.
Food Engineering Department, Faculty of Engineering, Adana Science and Technology University, 01250, Adana, Turkey.
J Mass Spectrom. 2018 May;53(5):444-454. doi: 10.1002/jms.4074.
The principal purpose of the present work is to characterize the aroma, aroma-active, and anthocyanin profiles of Okuzgozu wines and to observe the effect of the pomace pressing technique on these parameters. A total of 58 and 59 volatile compounds were identified and quantified in free-run juice wine (FRW) and pressed pomace wine (PW). Alcohols were found as the most dominant group among aroma compounds followed by esters and acids. However, among all these compounds, only 11 and 13 of them could be considered as key odorants in aromatic extracts of FRW and PW, respectively. According to GC-MS-O analysis, ethyl octanoate (fruity), phenyl ethyl acetate (fruity), and 2-phenyl ethanol (flowery) were found as the main contributors to the overall scent of both wines. Beyond the aroma profiles, anthocyanin contents of both types of wines were also investigated, and total 14 and 15 anthocyanins were identified and quantified in FRW and PW. Malvidin-3-glycoside and its acetyl and coumaroyl forms were identified as the dominant anthocyanins in both wines. It is worth noting the pressing application (2.0 atm) led to an increase of some unpleasant notes in the aroma providing chemical, pharmacy, and fermented aromas in wine. On the other hand, the wines produced with pressed pomace presented higher amounts of anthocyanins.
本研究的主要目的是对奥库兹戈祖葡萄酒的香气、香气活性成分和花色苷谱进行表征,并观察果渣压榨技术对这些参数的影响。在自流汁葡萄酒(FRW)和压榨果渣葡萄酒(PW)中分别鉴定并定量了58种和59种挥发性化合物。在香气化合物中,醇类是最主要的类别,其次是酯类和酸类。然而,在所有这些化合物中,FRW和PW的芳香提取物中分别只有11种和13种可被视为关键气味物质。根据气相色谱 - 质谱 - 嗅觉分析,辛酸乙酯(果香)、苯乙酸乙酯(果香)和2 - 苯乙醇(花香)被发现是两种葡萄酒整体香气的主要贡献成分。除了香气谱,还对两种葡萄酒的花色苷含量进行了研究,在FRW和PW中分别鉴定并定量了总共14种和15种花色素苷。锦葵色素 - 3 - 糖苷及其乙酰化和香豆酰化形式被确定为两种葡萄酒中的主要花色苷。值得注意的是,压榨操作(2.0个大气压)导致葡萄酒香气中出现一些不愉快的气味,呈现出化学、药草和发酵香气。另一方面,压榨果渣酿造的葡萄酒花色苷含量更高。