Pan Lei, Yang Ke, Li Guigen, Ge Haibo
Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA.
Chem Commun (Camb). 2018 Mar 13;54(22):2759-2762. doi: 10.1039/c8cc00980e.
Transition metal-catalyzed direct C-H bond functionalization enabled by transient ligands has become an attractive topic. Here we report a palladium-catalyzed site-selective arylation of β-C(sp)-H bonds in aliphatic ketones with β-alanine as the transient ligand.
由瞬态配体实现的过渡金属催化的直接C-H键官能化已成为一个引人关注的课题。在此，我们报道了以β-丙氨酸作为瞬态配体，钯催化脂肪族酮中β-C(sp)-H键的位点选择性芳基化反应。
