Maritime Division, Defence Science and Technology, Fishermans Bend, VIC 3207, Australia.
Mathematical and Statistical Computing Laboratory, Office of Intramural Research, Center for Information Technology, National Institutes of Health, Bethesda, Maryland 20892, USA.
J Chem Phys. 2018 Feb 28;148(8):084103. doi: 10.1063/1.5011060.
We study trapping of particles diffusing on a flat surface by complex-shaped absorbers formed by periodic absorbing spikes protruding from absorbing circular cores. It is shown that a spiky absorber can be replaced by an equivalent, from the trapping point of view, circular absorber of properly chosen radius. A simple expression for the effective absorber radius in terms of the geometric parameters of the spiky absorber (the number and length of the spikes and the core radius) is derived. To check its accuracy and to establish the range of its applicability, we run Brownian dynamics simulations and obtain the mean lifetimes of particles diffusing inside a reflecting circle with different spiky absorbers placed in its center. These mean lifetimes are then compared with their counterparts given by the theory for equivalent circular absorbers. There is an excellent agreement between the lifetimes obtained by the two methods when the radius of the reflecting circle is sufficiently large.
我们研究了由从吸收圆形核突出的周期性吸收尖峰形成的复杂形状的吸收器对在平坦表面上扩散的粒子的捕获。结果表明,从捕获的角度来看,尖峰吸收器可以被等效的、具有适当选择的半径的圆形吸收器代替。本文推导出了一个简单的有效吸收器半径表达式,它与尖峰吸收器的几何参数(尖峰的数量和长度以及核半径)有关。为了检查其准确性并确定其适用范围,我们运行了布朗动力学模拟,并获得了在不同放置在其中心的尖峰吸收器的反射圆内扩散的粒子的平均寿命。然后,将这些平均寿命与等效圆形吸收器的理论对应物进行比较。当反射圆的半径足够大时,两种方法得到的寿命之间存在极好的一致性。