Mei Yanbo, Wu Dong-Jun, Borger Jaap E, Grützmacher Hansjörg
Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog Weg 1, Hönggerberg, 8093 Zürich, Switzerland.
Lehn Institute of Functional Materials (LIFM), School of Chemistry, Sun Yat-Sen University, 510275, Guangzhou, China.
Angew Chem Int Ed Engl. 2018 May 4;57(19):5512-5515. doi: 10.1002/anie.201802242. Epub 2018 Mar 30.
A simple synthesis of sodium 2-phosphanaphthalene-3-olate (1) based on the extrusion of N from phthalazine using Na[OCP] is reported. This heterocycle can be readily functionalized at the negatively charged oxygen center using a variety of electrophilic substrates. The coordination chemistry of both 1 and its neutral derivatives was explored, revealing their facile use as P-donor ligands for late-transition-metal complexes.
报道了一种基于使用Na[OCP]从酞嗪中挤出N来简单合成2-磷萘-3-醇钠（1）的方法。这种杂环可以使用多种亲电底物在带负电荷的氧中心轻松地进行官能化。对1及其中性衍生物的配位化学进行了探索，揭示了它们作为后过渡金属配合物的P供体配体的便捷用途。
