低价镁（I）催化的酮的氰基硅烷化反应。

Low-valent magnesium(i)-catalyzed cyanosilylation of ketones.

作者信息

Wang Weifan, Luo Man, Li Jia, Pullarkat Sumod A, Ma Mengtao

机构信息

College of Science, Nanjing Forestry University, Nanjing 210037, China.

Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

出版信息

Chem Commun (Camb). 2018 Mar 25;54(24):3042-3044. doi: 10.1039/c8cc00826d. Epub 2018 Mar 7.

DOI:10.1039/c8cc00826d

PMID:29513327

Abstract

The magnesium(i) complex [(Nacnac)Mg] was employed as a highly efficient catalyst for the cyanosilylation of a variety of ketones with trimethylsilyl cyanide under mild conditions. In contrast to the traditional stoichiometric use of magnesium(i) complexes, 1 provides the first example of a truly catalytic application of Mg(i) complexes.

摘要

镁（I）配合物[(Nacnac)Mg]被用作一种高效催化剂，用于在温和条件下使各种酮与三甲基硅基氰进行氰硅烷化反应。与传统的化学计量使用镁（I）配合物不同，1提供了镁（I）配合物真正催化应用的首个实例。