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沿 3D DNA 纳米管对金纳米粒子进行光开关图案化。

Photo-switchable patterning of gold nanoparticles along 3D DNA nanotubes.

机构信息

Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, China and Key Laboratory of Biochip Technology, Biotech and Health Care, Shenzhen Research Institute of City University of Hong Kong, Shenzhen 518057, China.

出版信息

Nanoscale. 2018 Mar 28;10(12):5431-5435. doi: 10.1039/c7nr09650j. Epub 2018 Mar 8.

Abstract

We have developed a reversible photoswitching platform based on 3D DNA nanotubes by integrating photoisomerizable azobenzene molecules along the edges. This would allow the reversible conformational changes of the nanotubes between linear and bent features and the switchable patterning of gold nanoparticles in response to UV/Vis irradiation. This work provides a new strategy to create reversibly reconfigurable transformative nanomaterials for potential applications in the fields of renewable energy, sensing, nanorobotics and nanomedicine.

摘要

我们通过在边缘处整合光致变色的偶氮苯分子,开发了一种基于 3D DNA 纳米管的可逆光开关平台。这将允许纳米管在直线和弯曲特征之间进行可逆的构象变化,并且可以响应 UV/Vis 照射对金纳米粒子进行可切换的图案化。这项工作为创建具有潜在应用于可再生能源、传感、纳米机器人和纳米医学等领域的可逆可重构转化纳米材料提供了一种新策略。

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