School of Chemistry, Monash University, Melbourne, Victoria, 3800, Australia.
Fakultät für Naturwissenschaften, Institut für Chemie, Professur Koordinationschemie, Technische Universität Chemnitz, 09107, Chemnitz, Germany.
Chemistry. 2018 May 7;24(26):6722-6726. doi: 10.1002/chem.201705981. Epub 2018 Apr 17.
Solid-state metathesis (SSM) reactions between Bi(NO ) ⋅5 H O and potassium benzene-1,2-disulfonate (=1,2-BDSK ), sodium benzene-1,3-disulfonate (=1,3-BDSNa ) allows access to the first 2D, {[Bi O (OH) (1-2BDS) (NO ) ⋅4 H O]⋅11 H O} and {[Bi O (OH) (1,3-BDS) ⋅12 DMSO]⋅3 DMSO⋅4 H O} , and 3D, {[Bi O (OH) (1,3-BDS) ⋅4 H O]⋅6 H O} , polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.
双(硝酸根)氧合五水合氧化铋与苯-1,2-二磺酸钾（=1,2-BDSK）和苯-1,3-二磺酸钠（=1,3-BDSNa）之间的固态复分解（SSM）反应，生成了首例二维，{[Bi O (OH) (1-2BDS) (NO ) ⋅4 H O]⋅11 H O}和{[Bi O (OH) (1,3-BDS) ⋅12 DMSO]⋅3 DMSO⋅4 H O}，以及 3D，{[Bi O (OH) (1,3-BDS) ⋅4 H O]⋅6 H O}，聚合物网络的磺酸盐封装多核铋氧/羟基化物簇。
