分子磁学中的异三金属配合物。
Heterotrimetallic complexes in molecular magnetism.
作者信息
Andruh Marius
机构信息
University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania.
出版信息
Chem Commun (Camb). 2018 Apr 5;54(29):3559-3577. doi: 10.1039/C8CC00939B.
PMID:29546909
Abstract
This paper reviews the most representative examples of heterometallic complexes containing three different paramagnetic metal ions, focusing on their magnetic properties. These compounds show a rich structural variety, ranging from discrete species to coordination polymers of various dimensionalities. The general synthetic strategies leading to heterotrimetallic complexes are discussed and illustrated.
摘要
本文综述了含有三种不同顺磁性金属离子的异金属配合物的最具代表性的例子，重点关注它们的磁性。这些化合物呈现出丰富的结构多样性，从离散的物种到各种维度的配位聚合物。文中讨论并举例说明了合成异三金属配合物的一般策略。
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