叠氮化物与 9-硼芴分子间插入反应生成 9,10-B,N-菲咯啉。
Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes.
机构信息
Baylor University, Department of Chemistry and Biochemistry, One Bear Place #97348, Waco, Texas 76798, USA.
出版信息
Chem Commun (Camb). 2018 Jun 19;54(50):6808-6811. doi: 10.1039/C8CC01529E.
PMID:29547215
Abstract
The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.
摘要
9-硼杂芴与有机叠氮化物的反应，要么发生α-氮插入和 N2 消除，要么发生γ-氮插入，分别在 9 位和 10 位生成相应的带有硼和氮的菲衍生物。
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