Wu Hui Qiong, Yan Chang Sheng, Luo Feng, Krishna Rajamani
School of Biology, Chemistry and Material Science , East China University of Technology , NanChang , Jiangxi 344000 , China.
College of Chemistry and Chemical Engineering , Hunan University of Science and Technology , XiangTan , HuNan 411201 , China.
Inorg Chem. 2018 Apr 2;57(7):3679-3682. doi: 10.1021/acs.inorgchem.8b00341. Epub 2018 Mar 21.
Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal-organic framework) material, the CH/CO separation ability for the resultant Ag NPs (nanoparticle)@FeO@MOF composite material, estimated from breakthrough calculations, is greatly enhanced by 2 times, and further magnified up to 3 times under visible light irradiation.
与用于提高气体分离性能的既定晶体工程方法不同,我们在此展示了一种独特的方法。与原始的金属有机框架(MOF)材料相比,通过突破计算估计,所得的银纳米颗粒(Ag NPs)@FeO@MOF复合材料的CH/CO分离能力大幅提高了2倍,并且在可见光照射下进一步放大至3倍。