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一步合成钴掺杂 MoS 纳米片作为酸性和碱性条件下全水分解的双功能电催化剂。

One-step synthesis of cobalt-doped MoS nanosheets as bifunctional electrocatalysts for overall water splitting under both acidic and alkaline conditions.

机构信息

Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China.

出版信息

Chem Commun (Camb). 2018 Apr 12;54(31):3859-3862. doi: 10.1039/c8cc00766g.

Abstract

Cobalt-doped MoS2 nanosheets were prepared via a facile hydrothermal method, exhibiting bifunctional activities of hydrogen and oxygen evolution reactions in both acidic and alkaline media. Cobalt doping not only improves the conductivity, decreasing the hydrogen adsorption free energy of MoS2 for HER, but also contributes catalytic active sites for OER.

摘要

通过简便的水热法制备了钴掺杂的 MoS2 纳米片,在酸性和碱性介质中均表现出析氢反应(HER)和析氧反应(OER)的双功能活性。钴掺杂不仅提高了导电性,降低了 HER 中 MoS2 的氢吸附自由能,而且还为 OER 提供了催化活性位点。

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