Yan Zhenwei, Guo Shuaihui, Tan Zhaojun, Wang Lijun, Li Gang, Tang Mingqi, Feng Zaiqiang, Yuan Xianjie, Wang Yingjia, Cao Bin
School of Mechanical Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450011, China.
School of Materials Science and Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450011, China.
Materials (Basel). 2024 Apr 3;17(7):1637. doi: 10.3390/ma17071637.
Water splitting is an important way to obtain hydrogen applied in clean energy, which mainly consists of two half-reactions: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, the kinetics of the OER of water splitting, which occurs at the anode, is slow and inefficient, especially in acid. Currently, the main OER catalysts are still based on noble metals, such as Ir and Ru, which are the main active components. Hence, the exploration of new OER catalysts with low cost, high activity, and stability has become a key issue in the research of electrolytic water hydrogen production technology. In this paper, the reaction mechanism of OER in acid was discussed and summarized, and the main methods to improve the activity and stability of non-noble metal OER catalysts were summarized and categorized. Finally, the future prospects of OER catalysts in acid were made to provide a little reference idea for the development of advanced OER catalysts in acid in the future.
水分解是获取应用于清洁能源的氢气的重要途径,它主要由两个半反应组成:析氢反应(HER)和析氧反应(OER)。然而,发生在阳极的水分解析氧反应动力学缓慢且效率低下,尤其是在酸性环境中。目前,主要的析氧反应催化剂仍然基于贵金属,如铱和钌,它们是主要的活性成分。因此,探索低成本、高活性和稳定性的新型析氧反应催化剂已成为电解水制氢技术研究中的关键问题。本文讨论并总结了酸性环境中析氧反应的反应机理,对提高非贵金属析氧反应催化剂活性和稳定性的主要方法进行了总结和分类。最后,对酸性环境中析氧反应催化剂的未来前景进行了展望,为未来开发先进的酸性析氧反应催化剂提供一些参考思路。