Ultrasonically facilitated adsorption of an azo dye onto nanostructures obtained from cellulosic wastes of broom and cooler straw.

In the present work, ultrasonically facilitated adsorption (UFA) of a cationic dye [Basic Red 46 (BR46)] was examined using cellulosic nanostructures obtained from broom and cooler straw. Although the exclusive application of the nanostructured broom resulted in the 43.51% adsorption of BR46, the UFA process gave rise to the substantial removal efficiency of about 93%. In the case of the nanostructured straw, the efficiency was increased from 36.9% to 55.7%. The UFA process for both adsorbents reached the equilibrium within 60 min which was shorter than the time for the only adsorption. According to the values of the mean free energy (E), the decolorization via the UFA process applying broom (15.81 kJ/mol) and straw (11.18 kJ/mol) nanostructures was occurred chemically. An insignificant loss in the adsorption capacity of both adsorbents was observed after three regeneration tests by means of 0.05 M hydrochloric acid, indicating the good reusability potential of the as-synthesized cellulosic nanostructures.