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中尺度胜过纳米尺度:用于改善硅太阳能电池光捕获、光吸收和栅极电导的金属中尺度接触形态

Mesoscale trumps nanoscale: metallic mesoscale contact morphology for improved light trapping, optical absorption and grid conductance in silicon solar cells.

作者信息

Saive Rebecca, Atwater Harry A

出版信息

Opt Express. 2018 Mar 19;26(6):A275-A282. doi: 10.1364/OE.26.00A275.

Abstract

We report on a computational study exploring the design of mesoscale metallic front contacts for solar cells. We investigated silver contact structures with circle, triangle and square cross-sections for various length scales and surface coverages. We found that for 'nanoscale' contacts with widths between 10 nm and 1000 nm, resonant coupling actually impairs light absorption in the semiconductor. Conversely, for 'mesoscale' contact widths > 1000 nm, the light interaction is determined by the geometric shadowing. We find that mesoscale silver contacts with triangular cross-section outperform other nanostructure morphologies in reducing shadow losses and yield contact transparency of >99% percent with sheet resistance <0.2 Ω/sq. Surprisingly, very densely spaced mesoscale silver triangular cross-section contacts can enhance the absorption of thin silicon/silver structures by up to 15% at a front contact coverage of 83%, due to light trapping by the front contact. Such structures can also maintain up to 100% absorption within the silicon, at a front contact coverage of 50%, relative to the same structure without metal.

摘要

我们报告了一项关于探索用于太阳能电池的中尺度金属正面接触设计的计算研究。我们研究了具有圆形、三角形和正方形横截面的银接触结构,涵盖各种长度尺度和表面覆盖率。我们发现,对于宽度在10纳米至1000纳米之间的“纳米尺度”接触,共振耦合实际上会损害半导体中的光吸收。相反,对于“中尺度”接触宽度大于1000纳米的情况,光相互作用由几何阴影决定。我们发现,具有三角形横截面的中尺度银接触在减少阴影损失方面优于其他纳米结构形态,并且在薄层电阻小于0.2Ω/□时,接触透明度超过99%。令人惊讶的是,非常密集排列的中尺度银三角形横截面接触在正面接触覆盖率为83%时,由于正面接触的光捕获作用,可使薄硅/银结构的吸收增强高达15%。相对于没有金属的相同结构,这种结构在正面接触覆盖率为50%时,也能在硅内保持高达100%的吸收率。

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