Department of Chemistry, South University of Science and Technology of China, Shenzhen, Guangdong 518055, P. R. China.
Chem Commun (Camb). 2018 Apr 12;54(31):3907-3910. doi: 10.1039/c8cc00780b.
Sulfoxides and cyclic ureas are photochemically deoxygenating solvents in which the oxidative stress could be released and efficient triplet-triplet annihilation photon upconversion (TTA-UC) can operate in air. Such solvents can be practically screened out by harnessing the property of photo-activated phosphorescence.
亚砜和环状脲是光解脱氧溶剂,其中氧化应激可以释放,并且可以在空气中有效地进行三重态-三重态湮灭光子上转换(TTA-UC)。通过利用光激活磷光的性质,可以实际筛选出这些溶剂。