电荷在基于1,2,3-三唑（鎓）的卤素键活化剂中的作用。
The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators.
作者信息
Dreger Alexander, Engelage Elric, Mallick Bert, Beer Paul D, Huber Stefan M
机构信息
Department of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
出版信息
Chem Commun (Camb). 2018 Apr 17;54(32):4013-4016. doi: 10.1039/c8cc00527c.
Abstract
The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.
摘要
研究了电荷对单阳离子和双阳离子三唑（鎓）基卤素键供体性能的影响。除了在卤化物抽象基准反应中的活性外，还通过X射线结构分析和等温滴定量热法对卤素键进行了评估。
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