Li De-Jing, Lei Song, Wang Yan-Yue, Chen Shumei, Kang Yao, Gu Zhi-Gang, Zhang Jian
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, PR China.
Dalton Trans. 2018 Apr 24;47(16):5558-5563. doi: 10.1039/c8dt00761f.
The design and development of the supercapacitors containing metal oxides and carbon materials is very important for energy-storage devices in laboratory and industry. In this study, we report a helical carbon tube material derived from epitaxial Cu-MOF coating on textile by calcination treatment. The electrochemical performance obtained from the cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and cyclic stability measurements indicates that such a hybrid carbon material with a unique structure has a very high areal capacitance of 1812 mF cm-2 at a current density of 1 mA cm-2, and the material also has a good recyclability of 90% after 2000 cycles. This study combines the advantages of MOF- and cotton textile-derived carbon materials, and this study can serve as a guidance to improve the capacitance performance of supercapacitors.
对于实验室和工业中的储能设备而言,含金属氧化物和碳材料的超级电容器的设计与开发至关重要。在本研究中,我们报道了一种通过煅烧处理从纺织品上的外延Cu-MOF涂层衍生而来的螺旋碳管材料。从循环伏安法(CV)、恒电流充放电(GCD)和循环稳定性测量中获得的电化学性能表明,这种具有独特结构的混合碳材料在1 mA cm-2的电流密度下具有1812 mF cm-2的非常高的面积电容,并且该材料在2000次循环后还具有90%的良好可回收性。本研究结合了MOF衍生碳材料和棉纺织品衍生碳材料的优点,可为提高超级电容器的电容性能提供指导。