通过亲核 C-N 键形成合成含 N 的五元杂芳基取代的 3,5-二取代 BODIPYs。
Synthesis of 3,5-Disubstituted BODIPYs Bearing N-Containing Five-Membered Heteroaryl Groups via Nucleophilic C-N Bond Formation.
机构信息
Department of Chemistry, Graduate School of Science and Technology , Niigata University , Nishi-ku, Niigata 950-2181 , Japan.
Department of Applied Chemistry, Graduate School of Science and Engineering , Doshisha University , Kyotanabe 610-0394 , Japan.
出版信息
J Org Chem. 2018 May 4;83(9):5274-5281. doi: 10.1021/acs.joc.8b00087. Epub 2018 Apr 17.
Aromatic substitution reactions were applied to the divergent synthesis of a series of symmetrically and unsymmetrically 3,5-disubstituted BODIPYs bearing N-heteroaryl groups. Furthermore, the effect of N-heteroaryl substituents at the 3- and 5-positions on the optical and photophysical properties of the BODIPY π-electron system was elucidated.
芳基取代反应被应用于一系列带有 N-杂芳基的对称和不对称 3,5-取代 BODIPYs 的发散合成。此外，还阐明了 3-位和 5-位 N-杂芳基取代基对 BODIPY π-电子体系的光学和光物理性质的影响。
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