硒苯取代 BODIPYs 及其线性寡聚物的合成及独特光学性质。
Synthesis and Unique Optical Properties of Selenophenyl BODIPYs and Their Linear Oligomers.
机构信息
Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.
Division of Molecular Science, Graduate School of Science and Technology , Gunma University , 1-5-1 Tenjin-cho , Kiryu , Gunma 376-8515 , Japan.
出版信息
J Org Chem. 2018 May 4;83(9):5331-5337. doi: 10.1021/acs.joc.8b00782. Epub 2018 Apr 19.
A series of selenophene-substituted boron-dipyrrin (BODIPY) monomers and selenophene-linked BODIPY oligomers was synthesized. The synthesized BODIPYs show good absorption/emission properties in the red to near-infrared region. Furthermore, some of the selenophenyl BODIPYs are not only useful fluorophores but also good photosensitizers to produce singlet oxygen.
合成了一系列噻吩取代的硼二吡咯（BODIPY）单体和噻吩连接的 BODIPY 齐聚物。合成的 BODIPY 具有良好的在红光至近红外区域的吸收/发射性能。此外，一些噻吩基 BODIPY 不仅是有用的荧光团，而且是产生单线态氧的良好光敏剂。
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