Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.
Division of Molecular Science, Graduate School of Science and Technology , Gunma University , 1-5-1 Tenjin-cho , Kiryu , Gunma 376-8515 , Japan.
J Org Chem. 2018 May 4;83(9):5331-5337. doi: 10.1021/acs.joc.8b00782. Epub 2018 Apr 19.
A series of selenophene-substituted boron-dipyrrin (BODIPY) monomers and selenophene-linked BODIPY oligomers was synthesized. The synthesized BODIPYs show good absorption/emission properties in the red to near-infrared region. Furthermore, some of the selenophenyl BODIPYs are not only useful fluorophores but also good photosensitizers to produce singlet oxygen.
合成了一系列噻吩取代的硼二吡咯（BODIPY）单体和噻吩连接的 BODIPY 齐聚物。合成的 BODIPY 具有良好的在红光至近红外区域的吸收/发射性能。此外，一些噻吩基 BODIPY 不仅是有用的荧光团，而且是产生单线态氧的良好光敏剂。
