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一种用于在完全水溶液中检测铜的比色和荧光探针。

A Colorimetric and Fluorescent Probe for the Detection of Cu in a Complete Aqueous Solution.

作者信息

Xu Jing, Wang Zuokai, Liu Caiyun, Xu Zhenghe, Zhu Baocun, Wang Ning, Wang Kun, Wang Jiangting

机构信息

School of Resources and Environment, University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization.

出版信息

Anal Sci. 2018;34(4):453-457. doi: 10.2116/analsci.17P517.

DOI:10.2116/analsci.17P517
PMID:29643309
Abstract

The fluorescent probe has become an important method for the detection of heavy metal ions. In the present work, a new and simple fluorescent probe, Cu-P, for detecting copper ion (Cu) was designed and synthesized. The probe has shown high sensitivity and selectivity toward Cu. The detection limit was 13 nM (based on the 3σ/slope). A significant color change from yellow to pink was observed; thus, the probe Cu-P could serve as a "naked-eye" indicator for Cu. Furthermore, the proposed probe was used to detect Cu in real water and soil extract samples, with the result being satisfactory. Therefore, our proposed probe would provide a promising method for the detection of Cu in the environment.

摘要

荧光探针已成为检测重金属离子的重要方法。在本工作中,设计并合成了一种新型且简单的用于检测铜离子(Cu)的荧光探针Cu-P。该探针对Cu表现出高灵敏度和选择性。检测限为13 nM(基于3σ/斜率)。观察到明显的颜色变化,从黄色变为粉红色;因此,探针Cu-P可作为Cu的“肉眼”指示剂。此外,所提出的探针用于检测实际水样和土壤提取物样品中的Cu,结果令人满意。因此,我们提出的探针将为环境中Cu的检测提供一种有前景的方法。

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