Werner Daniel, Bayer Uwe, Rad Nazli E, Junk Peter C, Deacon Glen B, Anwander Reiner
Institut für Anorganische Chemie, University of Tübingen (EKUT), Auf der Morgenstelle 18, 72076, Germany.
College of Science & Engineering, James Cook University, Townsville, Qld 4811, Australia.
Dalton Trans. 2018 May 1;47(17):5952-5955. doi: 10.1039/c8dt00338f.
Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ-η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.
同配物[La(Me₂pz)₃]ₙ（Me₂pz = 3,5 - 二甲基吡唑）是一种μ - η²:η⁵ - Me₂pz配位聚合物，其中镧原子具有12配位，处于不寻常的η⁵:η⁵ Me₂pz夹心结构中，而铈的同系物形成了一个分子型四金属笼[Ce₄(Me₂pz)₁₂]，具有六种不同的Me₂pz配位模式。
