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基于明胶-淀粉纳米粒子的智能可食用薄膜的制备及理化性能。

Preparation and physicochemistry properties of smart edible films based on gelatin-starch nanoparticles.

机构信息

Shandong Provincial Key Laboratory of Fine Chemicals, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China.

出版信息

J Sci Food Agric. 2018 Nov;98(14):5470-5478. doi: 10.1002/jsfa.9091. Epub 2018 Jun 10.

Abstract

BACKGROUND

Among the natural polymers able to form edible films, starch and gelatin (Gel) are potential sources. Corn starch is a polysaccharide widely produced around the world, and gelatin differs from other hydrocolloids as a fully digestible protein, containing nearly all the essential amino acids, except tryptophan. Based on this, with advantages such as abundance, relatively low cost, biodegradability, and edibility, studies considering alternative systems for food protection that utilize biopolymers have increased significantly in recent years.

RESULTS

A novel macromolecular crosslinker starch-BTCAD-NHS (starch-butanetetracarboxylic acid dianhydride-N-hydroxysuccinimide, SBN) was successfully prepared to modify gelatin film. Compared with the blank gelatin films, the resulting SBN-Gel films exhibited improved surface hydrophobicity, higher tense strength and elongation-at-break, lower Young's modulus values, greater opacity, poorer water vapour uptake properties and better anti-degradation capacity.

CONCLUSION

The modified gelatin film material with advanced properties obtained in this work was safe, stable eco-friendly and biorefractory, and was an ideal choice to form packaging in the food industry. Also, the crosslinking SBN-Gel coating was effective in reducing corruption and extending the shelf life of peeled apple substantially. © 2018 Society of Chemical Industry.

摘要

背景

在能够形成可食用薄膜的天然聚合物中,淀粉和明胶(Gel)是潜在的来源。玉米淀粉是一种在世界各地广泛生产的多糖,与其他水胶体不同,明胶是一种完全可消化的蛋白质,含有几乎所有必需氨基酸,除色氨酸外。基于此,具有丰富、相对低成本、可生物降解性和可食用性等优点,近年来,研究人员越来越关注利用生物聚合物替代系统来保护食品。

结果

成功制备了一种新型的高分子交联剂淀粉-BTCAD-NHS(淀粉-丁烷四羧酸二酐- NHS,SBN)来修饰明胶膜。与空白明胶膜相比,所得的 SBN-明胶膜表现出更高的表面疏水性、更高的拉伸强度和断裂伸长率、更低的杨氏模量值、更大的不透明度、更差的水蒸气吸收性能和更好的抗降解能力。

结论

本工作获得的具有先进性能的改性明胶膜材料安全、稳定、环保且具有生物抗性,是食品工业中形成包装的理想选择。此外,交联 SBN-明胶涂层可有效减少腐败,显著延长去皮苹果的保质期。 © 2018 化学工业协会。

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