KO 促进的酚与[60]富勒烯的 C4 选择性偶联反应：在无过渡金属条件下一锅法合成 4-[60]富勒醇。
KO Bu-Promoted C4 Selective Coupling Reaction of Phenols and [60]Fullerene: One-Pot Synthesis of 4-[60]Fullerephenols under Transition-Metal-Free Conditions.
机构信息
Department of Chemistry, Key Laboratory of Functional Inorganic Materials of Anhui Province , Anhui University , Hefei 230039 , P. R. China.
Department of Chemistry , University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China.
出版信息
J Org Chem. 2018 May 18;83(10):5431-5437. doi: 10.1021/acs.joc.8b00261. Epub 2018 May 4.
A KO Bu-promoted direct coupling reaction of phenols and [60]fullerene was disclosed. The reaction occurs exclusively at the C4-position of phenols with high regioselectivity and provides an efficient and inexpensive manner to various 4-[60]fullerephenols in good yields. The electrochemical properties of the products render the method attractive and valuable.
一种 KO Bu 促进的酚类和 [60]富勒烯的直接偶联反应被揭示。该反应在酚类的 C4-位具有高区域选择性地进行，为各种 4-[60]富勒酚类提供了高效且经济的方法，产率良好。产物的电化学性质使该方法具有吸引力和价值。
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