由二价铜（I）配位稳定的偶氮芳族自由基阴离子的首次结构表征。
The First Structural Characterization of an Azoaromatic Radical Anion Stabilized by Dicopper(I) Coordination.
作者信息
Doslik Nataša, Sixt Torsten, Kaim Wolfgang
机构信息
Institut für Anorganische Chemie der Universität, Pfaffenwaldring 55, D-70550 Stuttgart (Germany), Fax: (+49) 711-685-4165.
出版信息
Angew Chem Int Ed Engl. 1998 Sep 18;37(17):2403-2404. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2403::AID-ANIE2403>3.0.CO;2-J.
Abstract
Double chelate coordination of [Cu(Ph P) ] stabilizes the radical anion of 2,2'-azobis(5-chloropyrimidine), which exhibits a N-N bond length of 1.345(7) Å in the complex (see picture). This is consistent with a one-electron reduced azo functionality.
摘要
[Cu(Ph P) ]的双螯合配位作用使2,2'-偶氮双(5-氯嘧啶)的自由基阴离子得以稳定，该自由基阴离子在配合物中的N-N键长为1.345(7) Å（见图）。这与单电子还原的偶氮官能团相符。
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