Wolf Justin, Stüer Wolfram, Grünwald Claus, Werner Helmut, Schwab Peter, Schulz Michael
Institut für Anorganische Chemie der Universität, Am Hubland, D-97074 Würzburg (Germany), Fax: (+49) 931-888-4605.
BASF Aktiengesellschaft, Ammoniaklaboratorium, D-67056 Ludwigshafen.
Angew Chem Int Ed Engl. 1998 May 4;37(8):1124-1126. doi: 10.1002/(SICI)1521-3773(19980504)37:8<1124::AID-ANIE1124>3.0.CO;2-C.
An active role is played by MgCl during the conversion of the vinylidene precursor 2 into carbenes 3 (R=H, Ph; L=P(C H ) ). These complexes can be prepared in a convenient and very efficient one-pot synthesis and have a catalytic activity in metathesis comparable to that of Grubbs compound (Ph instead of CH R).
在亚乙烯基前体2转化为卡宾3（R = H，Ph；L = P(C₆H₅)₃）的过程中，MgCl发挥了积极作用。这些配合物可以通过便捷且高效的一锅法合成制备，并且在复分解反应中具有与格拉布催化剂（用Ph代替CH₂R）相当的催化活性。
