由十个小分子组件自组装形成纳米级大环配合物
Self-Assembly of Nanometer-Sized Macrotricyclic Complexes from Ten Small Component Molecules.
作者信息
Fujita Makoto, Yu Shu-Yan, Kusukawa Takahiro, Funaki Hidenori, Ogura Katsuyuki, Yamaguchi Kentaro
机构信息
Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8595 (Japan), Fax: (+81) 564-55-5245.
Department of Applied Chemistry, Faculty of Engineering, Chiba University, Yayoicho, Inageku, Chiba 263 (Japan).
出版信息
Angew Chem Int Ed Engl. 1998 Aug 17;37(15):2082-2085. doi: 10.1002/(SICI)1521-3773(19980817)37:15<2082::AID-ANIE2082>3.0.CO;2-0.
Nanometer-sized bowls: six metal centers and four tridentate ligands self-assemble in aqueous solution to give the macrotricycle 1, which has approximate dimensions of 3×2×2 nm. Another macrocycle (not shown), obtained with a different ligand, is of similar size and topology but differs considerably from 1 in its host-guest behavior.
纳米尺寸的碗状物
六个金属中心和四个三齿配体在水溶液中自组装形成大环化合物1，其尺寸约为3×2×2纳米。另一种大环化合物（未示出），由不同的配体制得，具有相似的大小和拓扑结构，但在主客体行为方面与1有很大不同。
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