[Mo S O (OH) (H O) ]：一种基于[Mo S O ]结构单元的环状分子簇。
[Mo S O (OH) (H O) ]: A Cyclic Molecular Cluster Based on the [Mo S O ] Building Block.
作者信息
Cadot Emmanuel, Salignac Bernadette, Halut Sabine, Sécheresse Francis
机构信息
Institut Lavoisier, UMR C 173 du CNRS, Université de Versailles Saint-Quentin, 45 avenue des Etats-Unis, 78035 Versailles (France), Fax: (+33) 1-39254381.
Université Pierre et Marie Curie, Paris (France).
出版信息
Angew Chem Int Ed Engl. 1998 Mar 16;37(5):611-613. doi: 10.1002/(SICI)1521-3773(19980316)37:5<611::AID-ANIE611>3.0.CO;2-O.
The pH-dependent self-condensation of the [Mo S O ] complex fragment gives the wheellike Mo cluster depicted on the right (ball-and-stick model; large balls: S, medium balls: O, small balls: Mo). Applying this synthetic strategy to other starting materials could provide access to other polyoxothiometalates with well-defined cavities.
[Mo S O ]络合物片段的pH依赖性自缩合生成了右侧所示的轮状钼簇（球棍模型；大球：S，中球：O，小球：Mo）。将这种合成策略应用于其他起始原料可能会得到具有明确空腔的其他多氧硫金属酸盐。
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