碳水化合物-芳烃相互作用直接调控水溶性柔性糖环的构象平衡。
Carbohydrate-Arene Interactions Direct Conformational Equilibrium of a Flexible Glycophane in Water.
作者信息
Morales Juan Carlos, Penadés Soledad
机构信息
Instituto de Investigaciones Químicas, CSIC, Isla de la Cartuja, Américo Vespucio s/n, E-41092 Seville (Spain), Fax: (+34) 95-446-0565.
出版信息
Angew Chem Int Ed Engl. 1998 Mar 16;37(5):654-657. doi: 10.1002/(SICI)1521-3773(19980316)37:5<654::AID-ANIE654>3.0.CO;2-X.
Abstract
Water, the flexibility of the maltose molecule, and sugar/arene interactions are responsible for the equilibrium between a folded (I) and nonfolded (II) conformation in a glycophane (III is an intermediate). Glycophanes are cyclodextrin-cyclophane hybrids, which are of interest as models of receptors.
摘要
水、麦芽糖分子的柔韧性以及糖/芳烃相互作用决定了糖基杯芳烃（III为中间体）中折叠构象（I）和非折叠构象（II）之间的平衡。糖基杯芳烃是环糊精-杯芳烃杂化物，作为受体模型具有重要意义。
Zotero 插件