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同步双活性聚合：一种制备嵌段共聚物和接枝共聚物的新型一步法。

Simultaneous Dual Living Polymerizations: A Novel One-Step Approach to Block and Graft Copolymers.

作者信息

Mecerreyes David, Moineau Georges, Dubois Philippe, Jérôme Robert, Hedrick James L, Hawker Craig J, Malmström Eva E, Trollsas Mikael

机构信息

Center for Education and Research on Macromolecules (CERM), University of Liege, Sart-Tilman, B6, 4000 Liège (Belgium)., Fax: (+32) 4-3663-497.

Center for Polymeric Interfaces and Macromolecular Assemblies, IBM Almaden Research Center, 650 Harry Road, San Jose, CA, 95120-6099 (USA), Fax: (+1) 408-9273 310.

出版信息

Angew Chem Int Ed Engl. 1998 May 18;37(9):1274-1276. doi: 10.1002/(SICI)1521-3773(19980518)37:9<1274::AID-ANIE1274>3.0.CO;2-J.

DOI:10.1002/(SICI)1521-3773(19980518)37:9<1274::AID-ANIE1274>3.0.CO;2-J
PMID:29711216
Abstract

Just one step is required for the synthesis of block copolymers by simultaneous "living"/controlled ring-opening and radical polymerization initiated by a difunctional (A-B) compound (shown schematically on the right).

摘要

通过由双官能（A-B）化合物引发的同时“活性”/可控开环聚合和自由基聚合来合成嵌段共聚物仅需一步（如右侧示意图所示）。

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