Multiple Ga-Ga Bonding Character in Na [Ga(GaTrip ) ], and a Comparison with Neutral Ga(GaTrip ) (Trip=2,4,6-iPr C H ).
作者信息
Wehmschulte Rudolf J, Power Philip P
机构信息
Department of Chemistry, University of California, Davis, CA 95616 (USA), Fax: (+1) 530-752-8995.
出版信息
Angew Chem Int Ed Engl. 1998 Dec 4;37(22):3152-3154. doi: 10.1002/(SICI)1521-3773(19981204)37:22<3152::AID-ANIE3152>3.0.CO;2-7.
Abstract
Delocalized over the Ga framework, the two electrons are lost in the oxidation of Na [Ga(GaTrip ) ] to Ga(GaTrip ) . This leads to a lengthening of the Ga-Ga bond by about 0.08 Å. Ar=Trip=2,4,6-iPr C H .
摘要
Zotero 插件