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Synthesis of Tri- and Tetracoordinate Phosphorus Compounds Containing a PCF Group by Nucleophilic Trifluoromethylation of the Corresponding PF Compounds.

作者信息

Tworowska Izabela, Dąbkowski Wojciech, Michalski Jan

机构信息

Centre of Molecular and Macromolecular Studies Polish Academy of Sciences 90-363 Łódź, Sienkiewicza 112 (Poland) Fax: (+48) 42 684-71-26.

出版信息

Angew Chem Int Ed Engl. 2001 Aug 3;40(15):2898-2900. doi: 10.1002/1521-3773(20010803)40:15<2898::AID-ANIE2898>3.0.CO;2-I.

DOI:10.1002/1521-3773(20010803)40:15<2898::AID-ANIE2898>3.0.CO;2-I
PMID:29711973
Abstract

A new way of forming P-C bonds: Catalytic amounts of F ions facilitate the reaction of P -F compounds with CF SiMe to give P -CF compounds. These compounds can also be obtained in a one-pot procedure from P -OAr precursors (also shown).

摘要

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