Synthesis of Tri- and Tetracoordinate Phosphorus Compounds Containing a PCF Group by Nucleophilic Trifluoromethylation of the Corresponding PF Compounds.
作者信息
Tworowska Izabela, Dąbkowski Wojciech, Michalski Jan
机构信息
Centre of Molecular and Macromolecular Studies Polish Academy of Sciences 90-363 Łódź, Sienkiewicza 112 (Poland) Fax: (+48) 42 684-71-26.
出版信息
Angew Chem Int Ed Engl. 2001 Aug 3;40(15):2898-2900. doi: 10.1002/1521-3773(20010803)40:15<2898::AID-ANIE2898>3.0.CO;2-I.
Abstract
A new way of forming P-C bonds: Catalytic amounts of F ions facilitate the reaction of P -F compounds with CF SiMe to give P -CF compounds. These compounds can also be obtained in a one-pot procedure from P -OAr precursors (also shown).
摘要
Zotero 插件