State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing, 100083, China.
Petroleum Exploration and Production Research Institute, China Petroleum & Chemical Corporation (SINOPEC), Beijing, 100083, China.
Sci Rep. 2018 May 3;8(1):7014. doi: 10.1038/s41598-018-25104-5.
A consensus has been reached through previous studies that organic matter (OM) pores are crucial to porosity in many shale gas reservoirs; however, their origins and types remain controversial. Here, we report the OM pore types hosted in algae, bitumen, graptolite and other fossil fragments in the Wufeng-Longmaxi Formations of the Sichuan Basin, Southwest China. Algae types mainly include multicellular algae, unicellular algae, etc. The OM pores in multicellular algae usually exhibit irregular, bubble-like, spherical and/or elliptical profiles, and their diameters vary between 300 and 800 nm. The shapes of the OM pores in unicellular algae are either irregular or oval, and the pores are hundreds of nanometres in size. The pores associated with solid bitumen are sporadic, isolated and variable in size, ranging from 500 nm to 3 μm. The pores in the graptolite, sponge spicule, radiolarian and other fossil fragments are much smaller and fewer. The pores may only have developed in the surface of the graptolite and bitumen by filling in the biological cavity of the sponge spicule. These new findings provide stronger evidence that multicellular algae are the main hydrocarbon generating organisms of OM pores development.
先前的研究已经达成共识,有机质(OM)孔隙对许多页岩气储层的孔隙度至关重要;然而,其起源和类型仍存在争议。在这里,我们报告了在中国西南四川盆地五峰-龙马溪组中,藻类、沥青质、笔石和其他化石碎片中存在的 OM 孔隙类型。藻类类型主要包括多细胞藻类、单细胞藻类等。多细胞藻类中的 OM 孔隙通常呈现不规则、气泡状、球形和/或椭圆形,其直径在 300 至 800nm 之间。单细胞藻类中的 OM 孔隙形状不规则或椭圆形,孔隙大小为数百纳米。与固体沥青质相关的孔隙是零星的、孤立的且大小不一,范围从 500nm 到 3μm。笔石、海绵骨针、放射虫和其他化石碎片中的孔隙要小得多,也少得多。这些孔隙可能仅通过填充海绵骨针的生物腔在笔石和沥青质的表面发育。这些新发现为多细胞藻类是 OM 孔隙发育的主要烃类生成生物体提供了更强有力的证据。