A Dimeric η ,η -Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti-Ge-Ge-Ti Bond.
作者信息
Dong Zhaowen, Janka Oliver, Kösters Jutta, Schmidtmann Marc, Müller Thomas
机构信息
Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Carl von Ossietzky-Str. 9-11, 26129, Oldenburg, Germany.
Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstraße 30, 48149, Münster, Germany.
出版信息
Angew Chem Int Ed Engl. 2018 Jul 9;57(28):8634-8638. doi: 10.1002/anie.201804447. Epub 2018 Jun 12.
Dimeric germole dianion bridged Ti and Zr complexes have been synthesized. In these complexes, the germole dianion adopts a formal η ,η coordination to the two metal centers. The bonding situation in these bridged dimers is dominated by a covalent Ge-Ge interaction that results, for example, in a strong antiferromagnetic coupling of the d Ti centers.
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