School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China.
Org Biomol Chem. 2018 May 30;16(21):3881-3884. doi: 10.1039/c8ob00841h.
An efficient Fe(NO3)3·9H2O promoted ortho-nitration reaction of aniline derivatives has been developed. This reaction may go through a nitrogen dioxide radical (NO2˙) intermediate, which is generated by the thermal decomposition of iron(iii) nitrate. The practicality of the present method using nontoxic and inexpensive iron reagents has been shown by the broad substrate scope and applications.
一种高效的 Fe(NO3)3·9H2O 促进的苯胺衍生物的邻位硝化反应已经被开发出来。这个反应可能经历一个二氧化氮自由基（NO2˙）的中间体，它是由硝酸铁的热分解产生的。本方法使用无毒且廉价的铁试剂的实用性已经通过广泛的底物范围和应用得到了证明。
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