亚硫酸盐和亚铁氰化物促进的氢氰酸光还原同系化反应。

MRC Laboratory of Molecular Biology, Francis Crick Avenue, Cambridge Biomedical Campus, Cambridge, CB2 0QH, UK.

Chem Commun (Camb). 2018 May 29;54(44):5566-5569. doi: 10.1039/c8cc01499j.

Photoredox cycling during UV irradiation of ferrocyanide ([FeII(CN)6]4-) in the presence of stoichiometric sulfite (SO32-) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acids.

在亚硫酸根（SO32-）存在下，亚铁氰化物 ([FeII(CN)6]4-) 在紫外线照射下的光氧化还原循环被证明是一种非常有效的方法，可以将氢氰酸（HCN）还原同化为简单糖以及羟基酸和氨基酸的前体。