Kratish Yosi, Kostenko Arseni, Kaushansky Alexander, Tumanskii Boris, Bravo-Zhivotovskii Dmitry, Apeloig Yitzhak
Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa, 32000, Israel.
Angew Chem Int Ed Engl. 2018 Jul 2;57(27):8275-8279. doi: 10.1002/anie.201805107. Epub 2018 Jun 6.
The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt-HgSiR bond of a mercury-substituted platinum(II) complex. The Pt radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.
首个以铂（I）为中心的持久性自由基是通过汞取代的铂（II）配合物的Pt-HgSiR键的均裂产生的。该铂自由基通过电子顺磁共振光谱、化学捕获实验和密度泛函理论（DFT）计算进行了表征。
