Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Institution of Functional Organic Molecules and Materials, School of Chemistry & Chemical Engineering , Liaocheng University , Liaocheng 252059 , P. R. China.
Advanced Research Institute of Multidisciplinary Science, Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry & Chemical Engineering , Beijing Institute of Technology , Beijing 100081 , P. R. China.
Org Lett. 2018 Jun 1;20(11):3332-3336. doi: 10.1021/acs.orglett.8b01238. Epub 2018 May 17.
A series of bibenzo[ b][1,4]thiazines with various functional groups has been synthesized by a free-radical condensation reaction. Bibenzo[ b][1,4]thiazines were obtained in moderate to good yield (up to 85%) through a one-step reaction of readily available 2,2'-dithiodianiline and methyl aryl ketones with AIBN as radical initiator in HOAc. Bibenzo[ b][1,4]thiazines exhibit diversiform solid-state packing.
通过自由基缩合反应，合成了一系列带有各种官能团的双苯并[b][1,4]噻嗪。通过一步反应，使用 AIBN 作为自由基引发剂，在 HOAc 中，很容易获得的 2,2'-二硫二苯胺和甲基芳基酮，得到了中等至良好产率（高达 85%）的双苯并[b][1,4]噻嗪。双苯并[b][1,4]噻嗪呈现出多样化的固态堆积方式。
