基于二价芳香锡配合物的异双核三明治型配合物。

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand.

机构信息

Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, 338-8570, Japan.

出版信息

Dalton Trans. 2018 Jul 10;47(27):8892-8896. doi: 10.1039/c8dt01455h.

DOI:10.1039/c8dt01455h

PMID:29774331

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru-Rh complex exhibits an electronic property different from those of the corresponding Ru-Ru and Rh-Rh complexes. The Ru-Rh complex can be decomposed in ionic liquids to metal nanoparticles.

摘要

一种中性的杂双三明治型锡ole 配合物是通过阴离子钌茂与[Rh(cod)Cl]2（cod=1,5-环辛二烯）的反应制备的，所得的 Ru-Rh 配合物表现出与相应的 Ru-Ru 和 Rh-Rh 配合物不同的电子性质。Ru-Rh 配合物可以在离子液体中分解为金属纳米粒子。