一种多功能的 Eu-CP 作为可回收的发光探针，用于高灵敏度检测 Fe/Fe、CrO 和硝基芳香族爆炸物。

A multifunctional Eu-CP as a recyclable luminescent probe for the highly sensitive detection of Fe/Fe, CrO, and nitroaromatic explosives.

机构信息

Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China.

出版信息

Dalton Trans. 2018 Jun 5;47(22):7480-7486. doi: 10.1039/c8dt01518j.

DOI:10.1039/c8dt01518j

PMID:29786100

Abstract

A novel 2D lanthanide coordination polymer {Eu-CP (1)} based on a 3-bis(3-carboxyphenyl)imidazolium (L) ligand was successfully assembled through a solvothermal method. Luminescence tests indicate that 1 has excellent selectivity and sensitivity to detect Fe3+/Fe2+, Cr2O72-, and a series of nitroaromatic explosives. Interestingly, 1 can effectively distinguish CrVI anions (CrO42-/Cr2O72-), which is difficult for most of the reported CPs. Furthermore, in the detection process, 1 can be simply and quickly regenerated and reused at least five times. As far as we know, 1 is the first multifunctional Eu-CP used as a luminescent probe to detect Fe3+/Fe2+, Cr2O72-, and a series of nitroaromatic explosives (NAEs) based on the imidazolium derivative.

摘要

一种基于 3-双(3-羧基苯基)咪唑啉（L）配体的新型二维镧系配合物{Eu-CP(1)}通过溶剂热法成功组装。发光测试表明，1 对 Fe3+/Fe2+、Cr2O72-和一系列硝基芳烃炸药具有优异的选择性和灵敏度。有趣的是，1 可以有效区分 CrVI 阴离子（CrO42-/Cr2O72-），这对于大多数报道的 CPs 来说是很难的。此外，在检测过程中，1 可以简单快速地再生和重复使用至少五次。据我们所知，1 是第一个基于咪唑啉衍生物的多功能 Eu-CP，可用作发光探针来检测 Fe3+/Fe2+、Cr2O72-和一系列硝基芳烃炸药（NAEs）。