Japan Broadcasting Corporation (NHK), Science & Technology Research Laboratories, 1-10-11, Kinuta, Setagaya-ku, Tokyo, 157-8510, Japan.
Nippon Shokubai Co., Ltd., 5-8 Nishi Otabi-cho, Suita, Osaka, 564-8512, Japan.
Adv Mater. 2018 Jul;30(28):e1706768. doi: 10.1002/adma.201706768. Epub 2018 May 29.
Although organic light-emitting diodes (OLEDs) are promising for use in applications such as in flexible displays, reports of long-lived flexible OLED-based devices are limited due to the poor environmental stability of OLEDs. Flexible substrates such as plastic allow ambient oxygen and moisture to permeate into devices, which degrades the alkali metals used for the electron-injection layer in conventional OLEDs (cOLEDs). Here, the fabrication of a long-lived flexible display is reported using efficient and stable inverted OLEDs (iOLEDs), in which electrons can be effectively injected without the use of alkali metals. The flexible display employing iOLEDs can emit light for over 1 year with simplified encapsulation, whereas a flexible display employing cOLEDs exhibits almost no luminescence after only 21 d with the same encapsulation. These results demonstrate the great potential of iOLEDs to replace cOLEDs employing alkali metals for use in a wide variety of flexible organic optoelectronic devices.
尽管有机发光二极管 (OLED) 在柔性显示器等应用中具有广阔的前景,但由于 OLED 的环境稳定性较差,报道的长寿命柔性 OLED 基器件有限。柔性基底如塑料允许环境氧气和水分渗透到器件中,这会降解传统 OLED(cOLED)中用于电子注入层的碱金属。在这里,报道了使用高效稳定的倒置 OLED(iOLED)制造长寿命柔性显示器的方法,其中可以在不使用碱金属的情况下有效注入电子。采用 iOLED 的柔性显示器在简化封装的情况下可以发光超过 1 年,而采用 cOLED 的柔性显示器在相同封装下仅 21 天后几乎没有发光。这些结果表明,iOLED 具有取代使用碱金属的 cOLED 的巨大潜力,可用于各种柔性有机光电设备。