School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.
Chem Commun (Camb). 2018 Jun 19;54(50):6931-6934. doi: 10.1039/c8cc02423e.
In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.
在这项工作中，展示了一种几何受限的膦阳离子的合成。与之前报道的膦阳离子不同，该阳离子中 P 中心的几何约束使其具有双亲性，并可与小分子如 H2O、ROH 和 NH3 反应。
