具有两亲性的几何受限膦翁阳离子。
Ambiphilic geometrically constrained phosphenium cation.
机构信息
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.
出版信息
Chem Commun (Camb). 2018 Jun 19;54(50):6931-6934. doi: 10.1039/c8cc02423e.
PMID:29862397
Abstract
In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.
摘要
在这项工作中，展示了一种几何受限的膦阳离子的合成。与之前报道的膦阳离子不同，该阳离子中 P 中心的几何约束使其具有双亲性，并可与小分子如 H2O、ROH 和 NH3 反应。
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