Department of Chemistry, Graduate School of Science, Kobe University, Kobe, Hyogo, 657-8501, Japan.
Coordinated Center for UEC Research Facilities, The University of Electro-Communications, Chofu, Tokyo, 182-8585, Japan.
Chemistry. 2018 Jul 5;24(38):9490-9493. doi: 10.1002/chem.201801365. Epub 2018 Jun 21.
Ruthenium-containing organometallic ionic liquids with the B(CN) anion were developed that generate microporous amorphous coordination polymers upon UV irradiation. UV light irradiation of [Ru(C H )(C H R)][B(CN) ] (R=butyl, ethyl, octyl) quantitatively generated a yellow powder of a coordination polymer with the formula [Ru(C H ){B(CN) }] . In this reaction, the arene ligand is eliminated by UV irradiation and coordination polymer is formed by coordination of the cyano groups of the anion to the Ru ion. The photogenerated solids exhibited nitrogen absorption properties due to their microporous structure. This paper proposes a method to fabricate functional coordination polymers by photoirradiation of liquids.
开发了含钌的有机金属离子液体与 B(CN)阴离子，其在紫外光照射下生成微孔无定形配位聚合物。UV 光辐照[Ru(C H )(C H R)]B(CN) 定量生成黄色粉末的配位聚合物，其化学式为[Ru(C H ){B(CN) }] 。在这个反应中，芳基配体被 UV 光辐照消除，阴离子的氰基与 Ru 离子配位形成配位聚合物。光致固态由于其微孔结构表现出氮吸收性质。本文提出了一种通过光照液体制备功能配位聚合物的方法。
