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可回收的方格子（sql）拓扑配位网络的无孔相与多孔相之间的转换。

Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network.

机构信息

Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick, Republic of Ireland.

出版信息

Chem Commun (Camb). 2018 Jun 21;54(51):7042-7045. doi: 10.1039/c8cc03838d.

DOI:10.1039/c8cc03838d
PMID:29873349
Abstract

A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.

摘要

无孔方格子（sql）配位网络[Co(bipy)2(NCS)2]n（sql-1-Co-NCS）表现出可循环的 CO2 响应开关性能。吸附等温线呈阶梯状，具有中等滞后，温度可控且饱和吸存量固定。这种很少见的开关性能为气体存储提供了出色的工作容量的前景。

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