Center for Soft Condensed Matter Physics and Interdisciplinary Research, Soochow University, Suzhou, 215006, P. R. China.
Soft Matter. 2018 Jun 20;14(24):5092-5097. doi: 10.1039/c8sm00371h.
Density-dependent speed is studied in a two-dimensional active colloid in which the colloidal particles are propelled by an external electric field via a Quincke rotation. Above the critcal electric field, dense dynamic clusters form spotaneously, in which the particles are highly aligned in velocity and move much faster than isolated units. Detailed observations on pair collision reveal that the alignment of velocity is induced by the long-ranged hydrodynamic interactions and the improvement of speed in the clusters arises from pair aligning in which two particles are closely paired and rotate synchronically. In the aligning state, the short-range in-plane dipole-dipole attraction enhances the rotation torque and gives rises to a larger rolling speed. The pair aligning becomes difficult and unstable at high electric field where the normal dipole-dipole repulsion becomes dominant. As a consequence, the dependence of speed on density becomes weak increasingly upon the increase of the electric field. This result offers an interpretation for the discrepancy between our and previous observations on Quincke rollers.
密度相关的速度研究在二维活性胶体中进行,其中胶体颗粒通过 Quincke 旋转在外电场作用下推进。在临界电场之上,密集的动态簇会自发形成,其中颗粒在速度上高度对齐,移动速度比孤立单元快得多。对配对碰撞的详细观察表明,速度的对齐是由长程流体动力相互作用引起的,而在簇中的速度提高则源于配对对齐,其中两个颗粒紧密配对并同步旋转。在对齐状态下,短程面内偶极子-偶极子吸引力增强了旋转扭矩,并导致更大的滚动速度。在电场较高的情况下,正常偶极子-偶极子排斥作用变得占主导地位,因此配对对齐变得困难且不稳定。因此,随着电场的增加,速度对密度的依赖性越来越弱。这一结果为我们与之前关于 Quincke 辊的观察结果之间的差异提供了一种解释。