Light harvesting and charge management by NiS modified metal-organic frameworks and rGO in the process of photocatalysis.

Harvesting and charge management is obtained by means of NiS modified Metal-organic Frameworks (MOF) and rGO, namely, the Uio-66 (Zr)/rGO combined with NiS photocatalyst was successfully prepared with the solvothermal method. The NiS acted as the electron transfer agent greatly improve the electrons transmission from the excited state dye to the rGO/MOF surface for proton reduction reaction. The hydrogen production amount over EY-sensitized rGO/MOF/NiS photocatalyst has reached 280 μmol for 5 h, which is about 14 times than that of the pure NiS photocatalyst and 185 times than that of the pure rGO/MOF photocatalyst under visible light irradiation (λ ≥ 420 nm). In the composite, the rGO acts as electron-transfer mediator and NiS serves as H-evolution active site. A series of studies shown that the NiS modified MOF and rGO provided more active sites and improved the efficiency of photo-generated charge separation by means of several characterizations such as SEM, XRD, XPS, Element Mapping, UV-vis DRS, BET, Photocurrent, Voltammetric Scanning, Fluorescence Spectra and FTIR. and the results of which were in good agreement with each other. The photoelectron migration rate and photogenerated charge separation efficiency of the composite can be obviously increased with graphene as a good electron acceptor and transfer medium and NiS as hydrogen producing active site.