High resolution spatial and temporal evolution of dissolved gases in groundwater during a controlled natural gas release experiment.

Fugitive gas comprised primarily of methane (CH) with traces of ethane and propane (collectively termed C) may negatively impact shallow groundwater when unintentionally released from oil and natural gas wells. Currently, knowledge of fugitive gas migration, subsurface source identification and oxidation potential in groundwater is limited. To advance understanding, a controlled release experiment was performed at the Borden Research Aquifer, Canada, whereby 51m of natural gas was injected into an unconfined sand aquifer over 72days with dissolved gases monitored over 323days. During active gas injection, a dispersed plume of dissolved C evolved in a depth discrete and spatially complex manner. Evolution of the dissolved gas plume was driven by free-phase gas migration controlled by small-scale sediment layering and anisotropy. Upon cessation of gas injection, C concentrations increased to the greatest levels observed, particularly at 2 and 6m depths, reaching up to 31.5, 1.5 and 0.1mg/L respectively before stabilizing and persisting. At no time did groundwater become fully saturated with natural gas at the scale of sampling undertaken. Throughout the experiment the isotopic composition of injected methane (δC of -42.2‰) and the wetness parameter (i.e. the ratio of C to C) constituted excellent tracers for the presence of fugitive gas at concentrations >2mg/L. At discrete times C concentrations varied by up to 4 orders of magnitude over 8m of aquifer thickness (e.g. from <0.01 to 30mg/L for CH), while some groundwater samples lacked evidence of fugitive gas, despite being within 10m of the injection zone. Meanwhile, carbon isotope ratios of dissolved CH showed no evidence of oxidation. Our results show that while impacts to aquifers from a fugitive gas event are readily detectable at discrete depths, they are spatially and temporally variable and dissolved methane has propensity to persist.