手性希夫碱星形 Fe 配合物的圆二色性和磁性。基于连续形状度量的结构和磁性相关性。
Chiroptical and magnetic properties of star-shaped Fe complexes from chiral Schiff bases. Structural and magnetic correlations based on continuous shape measures.
机构信息
Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience and Nanotechnology (IN2UB), Universitat de Barcelona, Av. Diagonal 645, Barcelona-08028, Spain.
出版信息
Dalton Trans. 2018 Jun 25;47(25):8392-8401. doi: 10.1039/c8dt01684d.
PMID:29897079
Abstract
New chiral FeIII4 star-shaped complexes have been synthesized starting from enantiomerically pure Schiff bases and chiroptically and magnetically characterized. The structural and magnetic properties of the complete family of 40 Fe4 complexes reported in the literature have been analyzed in the search for synthetic and magnetostructural correlations.
摘要
新型手性 FeIII4 星型配合物是由对映体纯的希夫碱出发合成的，并对手性和磁性进行了表征。对文献中报道的完整的 40 个 Fe4 配合物家族的结构和磁性性质进行了分析，以寻找合成和磁结构相关性。
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