State Key Laboratory of Dairy Biotechnology, Technology Center, Bright Dairy & Food Co., Ltd., Shanghai 200436, China.
State Key Laboratory of Food Science and Technology, Jiangnan University, Wuxi 214122, China.
Int J Mol Sci. 2018 Jun 13;19(6):1747. doi: 10.3390/ijms19061747.
During heating, there are a lot of physical and chemical changes in milk components, which are mainly reflected in the changes of proteins. Calcium ions in milk react with proteins to precipitate or form gels, and the thermal stability of milk is affected by the type and content of calcium. In this study, different calcium-fortified milk systems were treated by rapid conventional heating (RCV) and microwave heating (MV) to evaluate the effects of forms and concentration of calcium in liquid milk on microwave absorption properties and thermal stability of milk. It was found that the concentration of calcium ions on microwave energy absorption is not a significant influence, while the forms affected the systems dramatically. The thermal stability of milk during MV is remarkably affected by the forms of calcium ions. When adding ionized calcium, the calcium-fortified milk systems had poor thermal stability and severe agglomeration of protein, while the addition of milk calcium had little effect and was almost free from protein coagulation. It could be speculated that the metal ions in the microwave field could create a strong vibration that could trigger protein agglomeration through the combination of the surrounding casein phosphorylates.
在加热过程中,牛奶成分会发生许多物理和化学反应,主要体现在蛋白质的变化上。牛奶中的钙离子与蛋白质发生反应沉淀或形成凝胶,而牛奶的热稳定性受到钙的类型和含量的影响。在本研究中,通过快速常规加热(RCV)和微波加热(MV)处理不同的钙强化牛奶体系,以评估液态奶中钙的形式和浓度对牛奶的微波吸收特性和热稳定性的影响。结果发现,钙离子浓度对微波能量吸收的影响不显著,而钙的形式则对体系有显著影响。在 MV 过程中,钙离子的形式对牛奶的热稳定性有显著影响。当添加离子钙时,钙强化牛奶体系的热稳定性差,蛋白质严重聚集,而添加乳钙几乎没有影响,几乎没有蛋白质凝结。可以推测,微波场中的金属离子可以通过与周围的酪蛋白磷酸肽结合产生强烈的振动,从而引发蛋白质聚集。