Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, 40225, Düsseldorf, Germany.
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Strasse 2, 24118, Kiel, Germany.
Chemistry. 2018 Sep 20;24(53):14048-14053. doi: 10.1002/chem.201802838. Epub 2018 Aug 22.
A strategy was developed to obtain from acetylenedicarboxylic acid either an acetylenedicarboxylate-based Zr metal-organic framework (MOF) with fcu topology or a halo-functionalized-MOF-801 through in situ ligand hydrohalogenation. The new materials feature exceptionally high hydrophilicity and CO /H adsorption energetics. The acetylenedicarboxylate linker and its functionalizable triple-bond discloses its potential in the engineering of microporous materials with targeted properties.
开发了一种策略，从乙炔二羧酸获得基于乙炔二羧酸的 fcu 拓扑结构的 Zr 金属有机骨架（MOF）或通过原位配体卤化原位卤化得到卤代官能化-MOF-801。新材料具有极高的亲水性和 CO/H 吸附能。炔二羧酸连接基及其可功能化的三键揭示了其在具有目标性能的微孔材料工程中的潜力。
