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基于镁铁氧体(MgFeO)纳米颗粒的磁性海藻酸钠珠的合成用于从水溶液中去除Sr(II):动力学、平衡和热力学研究。

Synthesis of magnetic alginate beads based on magnesium ferrite (MgFeO) nanoparticles for removal of Sr (II) from aqueous solution: kinetic, equilibrium and thermodynamic studies.

作者信息

Yakout Sobhy M, Hassan Mohamed R, Aly Mohamed I

机构信息

Hot Laboratories and Waste Management Centre, Atomic Energy Authority, P.O. 13759, Cairo, Egypt E-mail:

Nuclear Research Center, Atomic Energy Authority, P.O. 13759, Inshas, Cairo, Egypt.

出版信息

Water Sci Technol. 2018 Jun;77(11-12):2714-2722. doi: 10.2166/wst.2018.228.

Abstract

Novel magnetic alginate beads (MagAlgbeads) have been developed by incorporation of magnesium ferrite (MgFeO) in alginate beads with the aim of using them in the removal of strontium from aqueous solution. MagAlgbeads were characterized by transmission electron microscopy, scanning electron microscopy, X-ray fluorescence and Fourier transform infrared spectroscopy. The adsorption of strontium onto MagAlgbeads were found to depend on pH and strontium removal increases with increasing pH until pH is 6. Strontium adsorption kinetics run through pseudo-second-order model. Thermodynamically, strontium adsorption was endothermic and spontaneous. Langmuir isotherm gave good fitting for strontium removal with adsorption capacity of 505.5 mg/g. These results proved that the prepared MagAlgbeads are very efficient material for strontium adsorption.

摘要

通过将铁酸镁(MgFeO)掺入藻酸盐珠粒中,开发出了新型磁性藻酸盐珠粒(MagAlgbeads),目的是将其用于从水溶液中去除锶。通过透射电子显微镜、扫描电子显微镜、X射线荧光和傅里叶变换红外光谱对MagAlgbeads进行了表征。发现锶在MagAlgbeads上的吸附取决于pH值,并且随着pH值的增加,锶的去除率也会增加,直到pH值达到6。锶吸附动力学符合准二级模型。从热力学角度来看,锶的吸附是吸热且自发的。朗缪尔等温线对锶的去除具有良好的拟合效果,吸附容量为505.5 mg/g。这些结果证明,所制备的MagAlgbeads是用于锶吸附的非常有效的材料。

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